2. CERTIFICATE
Name: Class:
Roll No:
Institution:
This is certified to be the bonafidework of the student in the
“Chemistry” Laboratory during the academic year 2016-2017.
……………….
Teacher In-Charge
………………… …………….
Examiner’s Signature Principal
Date: ……………. Institution Rubber Stamp
3. ACKNOWLEDGEMENT
I wish to express my deep gratitude and sincere
thanks to Principal, Mr. P.V Sudhakaran for his
encouragement and for all the facilities that he
provided for this project work. I sincerely
appreciate this magnanimity by taking me into his
fold for which I shall remain indebted to her. I
extend my hearty thanks to Mrs. Seema Sharma
my chemistry teacher, who guided me to the
successful completion of this project. I take this
opportunity to express my deep sense of
gratitude for his invaluable guidance, constant
encouragement, and constructive comments,
sympathetic attitude and immense motivation,
which has sustained my efforts at all stages of this
project work.
4. Declaration
I do hereby declare that this chemistry
project work has been originally carried
under the guidance and supervision of
Mrs. Seema Sharma, head of chemistry
department, Kendriya Vidyalaya No.2
School,Agra Cantt, Agra (U.P).
5. Experiment – 1
Aim: To study the setting of mixtures of cement
with lime, sand, fly ash etc.
Requirements: Beakers, glass rod, weights,
small wooden boxes or empty match boxes. Lime, pit sand,
river sand, cement, fly ash, rice husk…
6. Introduction:
Cement is essentially a finely ground mixture of calcium
silicates (3Cao.SiO2) and aluminates (3Cao.Al2O3)
which sets to a hard mass treated with water. This
property makes cement capable of joining rigid masses
like bricks, stones, tiles etc. into coherent structures.
The cements have property of setting and hardening
under water due to certain physicochemical process
and are, therefore, called hydraulic cements. During
setting of cement, the physical changes taking place
are gel formation and crystallization and chemical
changes are hydration and hydrolysis. The process of
solidification of cement paste involves: (i) setting, and
(ii) hardening.
Setting is stiffening of the original plastic mass into
initial gel formation. After setting, hardening starts due
to gradual start of crystallization in the interior of the
mass. The strength developed by cement at any time
depends upon the amount of gel formed and the
extent of crystallization. A mixture of cement, sand,
small pieces of stone (gravel) and water is known as
concrete and sets to an extremely hard structure.
7. When cement is used for construction purposes, it is
always mixed with sand and little water to make a
pasty material called mortar. Here cement or lime
forms the binding material and function of sand is to
prevent shrinking and cracking and to increase the
bulk, thereby reducing the cost of the mortar. When
cement is used as the binding material it is called
cement mortar and when lime is used as the binder it is
called lime-mortar. Sand in addition to its other
functions also increases the adhesive qualities of the
binding material. Effect of quality of sand on setting of
cement mortar. Sand obtained from different sources
has different qualities. For example, sea sand obtained
from sea contains some unwanted salts and retards the
setting of cement and is unsuitable for making mortar.
On the other hand, pit sand obtained from pits in the
soil and river sand obtained from river bed are
considered excellent for preparing mortar and
concrete.
Effect of time on setting of cement mortar. Time has
an important role on the strength developed by
cement mortar. When a cement sand paste in the ratio
1:3 in water is allowed to dry, the strength of the solid
mass keeps on increasing with increase in the time
given for setting. It acquires nearly full strength in 28
days.
8. Procedure:-
1. Prepare the sets of mixtures of various compositions
as given in the observation table.
2. Take each of the mixtures in different beakers and
prepare their pastes by adding minimum quantity of
water.
3. Take 10 empty match-box inner cases and mark them
from 1 to 10.
4. Transfer the prepared pastes immediately into the
matchboxesand compact themby pressing with hand.
5. Spray water from time to time over the pastes so
that they are always moist.
6. Take out the slabs after three days and test for its
strength. For that hold a weight of 10g on the hand at a
fixed height (say 50 cm above the ground) and drop
the weight on the slab. See if the slab breaks or not. If
it does not break then take 20g weight and drop it
from the same height. This way keeps on increasing the
weight and note down the minimum weight required
to break the slab.
Observations:
9. Setting time allowed = 3 days.
Note: - The slab should be of 0.5 cm thickness, 2 cm
wide and 10 cm long.
Sl.No
Compositions of Mortar(Ratio
composition by volume)
Minimum
weight
required to
break the
slab.
Cement River
sand
Pit
sand
Lime Fly
ash
Rise
husk
……..gm.
1. 1 3 **** **** **** **** ……..gm.
2. 1 6 **** **** **** **** ……..gm.
3. 1 **** 3 **** **** **** ……..gm.
4. 1 **** 6 **** **** **** ……..gm.
5. 1 6 **** **** 1 **** ……..gm.
6. 2 9 **** **** 1 **** ……..gm.
7. 1 3 **** 1 **** **** ……..gm.
8. 1 3 **** 2 **** **** ……..gm.
9. 1 1 **** **** **** 1 ……..gm.
10 1 3 **** **** **** 2 ……..gm.
10. Experiment – 2
AIM: To study the setting of mixtures of cement with
sand, lime and fly-ash with respect to time and
strength.
Requirements: Beakers, glass rod, weights, small
wooden boxes or empty match boxes. Lime, pit sand,
river sand, cement, fly-ash, rice husk.
11. Procedure:-
1. Prepare mixtures of the various compositions as
given in the following observation table.
2. Take each of the mixtures in different beakers and
prepare their pastes by adding minimum quantity of
water.
3. Take 9 empty match-box inner cases and mark them
from 1 to 9.
4. Fill three cases with paste of each composition.
5. Spray water from time to time over the pastes so
that they remain moist all the time.
6. After three days take out one slab of each
composition and test for their strength by the method
described in previous experiment.
7. Similarly, take out a set of three slabs after 7 days
and then after 30 days and test for their strengths.
12. Observations:-
Note: - The slab should be of 0.5 cm thickness, 2 cm
wide and 10 cm long.
Conclusion: -The strength of the slab increases
with increase in the setting time allowed…!
S.No Composition of
mixture
Minimum weight require
to break the slab after
3 days 10 days 20days
Cement : River sand ……..gm ……..gm ……..gm
1:03
Cement: River sand: Fly-
ash
……..gm ……..gm ……..gm
2:09:01
Cement: River sand: Lime ……..gm ……..gm ……..gm
1:03:01