Direct synthesis of a {CoIII6FeIII6} dodecanuclear complex, revealing an unprecedented molecular structure type

Eduard N. Chygorin; Vladimir N. Kokozay; Irina V. Omelchenko; Oleg V. Shishkin; Ján Titiš; Roman Boča; Dmytro S. Nesterov

doi:10.1039/C5DT01149C

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Direct synthesis of a {Co ^III₆Fe ^III₆} dodecanuclear complex, revealing an unprecedented molecular structure type†

Eduard N. Chygorin,^a Vladimir N. Kokozay,^a Irina V. Omelchenko,^b Oleg V. Shishkin,^b Ján Titiš,^c Roman Boča^c and Dmytro S. Nesterov

*^d

Author affiliations

* Corresponding authors

^a Department of Inorganic Chemistry, Taras Shevchenko National University, Volodymyrska str. 64/13, Kyiv 01601, Ukraine

^b STC “Institute for Single Crystals” National Academy of Sciences of Ukraine, 60, Lenina Avenue, Kharkiv 61001, Ukraine

^c Department of Chemistry, FPV, University of SS Cyril and Methodius, 917 01 Trnava, Slovakia

^d Centro de Química Estrutural, Instituto Superior Técnico, Universidade de Lisboa, Avenida Rovisco Pais, 1049-001 Lisboa, Portugal
E-mail: dmytro.nesterov@tecnico.ulisboa.pt

Abstract

A novel heterometallic Co₆Fe₆ Schiff base complex, possessing an unprecedented {M₁₂(μ-X)₂₂} branched structure (according to the search via the Cambridge Structural Database), has been prepared using the “direct synthesis” approach and characterized by single crystal X-ray diffraction and magnetometry.

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Article information

DOI: https://doi.org/10.1039/C5DT01149C
Article type: Communication
Submitted: 23 Mar 2015
Accepted: 09 Apr 2015
First published: 20 May 2015

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Dalton Trans., 2015,44, 10918-10922

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Direct synthesis of a {Co^III₆Fe^III₆} dodecanuclear complex, revealing an unprecedented molecular structure type

E. N. Chygorin, V. N. Kokozay, I. V. Omelchenko, O. V. Shishkin, J. Titiš, R. Boča and D. S. Nesterov, Dalton Trans., 2015, 44, 10918 DOI: 10.1039/C5DT01149C

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