Best Dressed of the Week: Angela Simmons Slays at NYFW

Plus, must-see looks from Keke Palmer and more.

Fashionista - Angela Simmons gets glam in the front of the Spring/Summer 2015 Vivienne Tam fashion show during Mercedes-Benz Fashion Week at Lincoln Center in New York City.  (Photo: Larry Busacca/Getty Images for Mercedes-Benz Fashion Week)

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Angela Simmons - The Angela I Am designer takes on New York Fashion Week in this ultra cute frock. Angie's dress of choice to the Vivienne Tam show has a little class and a little sass. Peep the matching pumps, too! By Jazmine A. Ortiz(Photo: Larry Busacca/Getty Images for Mercedes-Benz Fashion Week)

Uzo Aduba - The Orange Is the New Black star can't seem to shake the color she wears regularly on the show. She stuns in an orange-and-black printed frock at the Vivienne Tam fashion show during NYFW.(Photo: Larry Busacca/Getty Images for Mercedes-Benz Fashion Week)

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Uzo Aduba - The Orange Is the New Black star can't seem to shake the color she wears regularly on the show. She stuns in an orange-and-black printed frock at the Vivienne Tam fashion show during NYFW.(Photo: Larry Busacca/Getty Images for Mercedes-Benz Fashion Week)

Zoe Kravitz - The actress does asymmetrical right! She dons a cascading-hem black Balenciaga dress to the Good Kill photo-call during the Venice Film Festival.(Photo: AA/Splash News)

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Zoe Kravitz - The actress does asymmetrical right! She dons a cascading-hem black Balenciaga dress to the Good Kill photo-call during the Venice Film Festival.(Photo: AA/Splash News)

Tamera Mowry - The Real co-host is red hot for an interview at SiriusXM Radio. The boldly colored, fitted frock certainly makes a statement.(Photo: Rommel Demano/Getty Images)

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Tamera Mowry - The Real co-host is red hot for an interview at SiriusXM Radio. The boldly colored, fitted frock certainly makes a statement.(Photo: Rommel Demano/Getty Images)

Jennifer Lopez - Fashion Rocks, the charity event where music and fashion collide, returned after a five-year hiatus, with bold fashion and even bigger stars. Here's a recap of the hottest style moments from the red carpet. Plus, check out more behind-the-scenes action on B*Real's Instagram page! By Jazmine A. OrtizJenny from the Block was made for the red carpet. She steps onto the scene at Barclays Center in a black Atelier Versace number complete with gold-plated detail, cutouts and a thigh-high slit. #YASSSS(Photo: Dimitrios Kambouris/Getty Images for Three Lions Entertainment)

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Jennifer Lopez - J.Lo shuts the red carpet down at Fashion Rocks. The Versace gown puts the "Booty" singer's best assets on display.(Photo: Dimitrios Kambouris/Getty Images for Three Lions Entertainment)

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Mila J - The singer/songwriter takes on the night in a sexy pantsuit paired with a plunging white top. (Photo: Stephen Lovekin/Getty Images for Three Lions Entertainment)

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Mila J - Also at Fashion Rocks, the singer-songwriter strikes gold in this printed pantsuit. The plunging neckline on her white blouse gives an added dose of sex appeal. (Photo: Stephen Lovekin/Getty Images for Three Lions Entertainment)

Photo By Photo: Stephen Lovekin/Getty Images for Three Lions Entertainment

Adrienne Bailon - The television personality breathes life into this simple outfit she sports at the US Open. A leopard-print crop top and black slacks are a no-fuss combo for any occasion.(Photo: IGGI / Splash News)

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Adrienne Bailon - The television personality breathes life into this simple outfit she sports at the US Open. A leopard-print crop top and black slacks are a no-fuss combo for any occasion.(Photo: IGGI / Splash News)

Photo By Photo: IGGI / Splash News

June Ambrose - The celebrity stylist serves monochromatic madness during NYFW! She attends the DKNY 30th Anniversary fashion show wearing this all-purple ensemble.(Photo: Cindy Ord/Getty Images for Mercedes-Benz Fashion Week)

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June Ambrose - The celebrity stylist serves monochromatic madness during NYFW! She attends the DKNY 30th Anniversary fashion show wearing this all-purple ensemble.(Photo: Cindy Ord/Getty Images for Mercedes-Benz Fashion Week)

Photo By Photo: Cindy Ord/Getty Images for Mercedes-Benz Fashion Week

Rita Ora - Hitting up the REVEAL Calvin Klein fragrance launch party, the songstress strikes a pose in a sleeveless leather dress and strappy stilettos. She compliments her look perfectly with bombshell waves and her signature red pout.  (Photo: Taylor Hill/Getty Images)

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Rita Ora - The "Black Widow" singer could easily be confused for a Marilyn Monroe look-alike. She attends the REVEAL Calvin Klein fragrance launch party in NYC wearing a leather LBD and strappy sandals.(Photo: Taylor Hill/Getty Images)

Keke Palmer - The Cinderella star shines like a princess in this adorable #OOTD. For InStyle's 20th Anniversary party, she turns it out in a shimmery blue Mantu skirt, Oscar Tiye pumps and a tank by Etre Cecile.(Photo: Rommel Demano/Getty Images)

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Keke Palmer - The Cinderella star shines like a princess in this adorable #OOTD. For InStyle's 20th Anniversary party, she turns it out in a shimmery blue Mantu skirt, Oscar Tiye pumps and a tank by Etre Cecile.(Photo: Rommel Demano/Getty Images)